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We found one dictionary that defines the word corset effect:

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  1. corset effect: Wiktionary

Definitions from Wiktionary (corset effect)

noun:  (organic chemistry, physical chemistry) With regard to a stable tetrahedrane derivative with four tertiary butyl substituents enveloping the tetrahedrane core, the theory that bonds in the core are prevented from breaking because this would force the substituents closer together, resulting in van der Waals strain.

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