Luis Alberto Arce Catacora (born 28 September 1963), often referred to as Lucho, is a Bolivian banker, economist, and politician serving as the 67th president of Bolivia since 2020.

Enrique Javier Arce Temple (born October 8, 1972) is a Spanish television and film actor.

Jorge Armando Arce Armenta (born July 27, 1979), best known as Jorge Arce, is a Mexican former professional boxer who competed from 1996 to 2014.

Billy Vladimir Arce Mina (born 12 July 1998) is an Ecuadorian footballer who plays either as a left winger or a forward.

Francisco Javier "Chiqui" Arce Rolón (born 2 April 1971) is a Paraguayan football manager and former player.

Aniceto Arce Ruiz de Mendoza (15 April 1824, in Tarija – 14 August 1906) was a Bolivian lawyer and politician who served as the 22nd president of Bolivia from 1888 to 1892.