Definitions from Wiktionary (captivate)

▸ verb:  (obsolete)
▸ verb:  To make (a person, an animal, etc.) a captive; to take prisoner; to capture, to subdue.
▸ verb:  (figuratively) To capture or control (the mind, etc.); to subdue, to subjugate.
▸ verb:  (figuratively) To attract and hold (someone's) attention and interest; to charm, to entrance, to fascinate, to enchain.
▸ adjective:  (also figuratively, obsolete) Made captive; taken prisoner; captured, subdued.
▸ Also see captivate

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