Usually means: Electrochemical cell generating electricity chemically.
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We found 9 dictionaries that define the word voltaic couple:

General (9 matching dictionaries)
  1. voltaic couple: Merriam-Webster
  2. voltaic couple: American Heritage Dictionary of the English Language
  3. voltaic couple: Collins English Dictionary
  4. voltaic couple: Wordnik
  5. voltaic couple: Wiktionary
  6. voltaic couple: Infoplease Dictionary
  7. voltaic couple: Dictionary.com
  8. voltaic couple: FreeDictionary.org
  9. voltaic couple: TheFreeDictionary.com

Definitions from Wiktionary (voltaic couple)

noun:  The pair of plates (made of different metals or other conductive materials), and separated by an electrolyte, which form a voltaic cell (in a battery, for example).

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