Might mean (unverified): Exchange of ligands between metal centers.
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We found 2 dictionaries that define the word transmetallation:

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  1. transmetallation: Wiktionary
  2. Transmetallation: Wikipedia, the Free Encyclopedia

Definitions from Wiktionary (transmetallation)

noun:  (organic chemistry) Any reaction in which one metal is exchanged for another in an organometallic compound.

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