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We found one dictionary that defines the word scorpionate:

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  1. scorpionate: Wiktionary

Definitions from Wiktionary (scorpionate)

adjective:  (chemistry, of a ligand) Being tridentate, so as to bind to a metal in a fac manner (or facial; said of an isomer when three of its ligands, when identical, occupy one face of an octahedron).
noun:  (chemistry) A ligand having a tridentate form.

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