Usually means: Ligand that binds multiple sites.
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We found 3 dictionaries that define the word polydentate:

General (2 matching dictionaries)
  1. polydentate: Merriam-Webster
  2. polydentate: Wiktionary

Science (1 matching dictionary)
  1. Chemistry Dictionary (No longer online)

Definitions from Wiktionary (polydentate)

adjective:  (chemistry, of a ligand) Coordinated to the central atom by several bonds; multidentate

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