Usually means: Bound state of two pions.
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We found 3 dictionaries that define the word pionium:

General (2 matching dictionaries)
  1. pionium: Wiktionary
  2. Pionium: Wikipedia, the Free Encyclopedia

Computing (1 matching dictionary)
  1. pionium: Encyclopedia

Definitions from Wiktionary (pionium)

noun:  (physics, chemistry) an exotic atom equivalent to a hydrogen atom with the proton replaced by a pion
noun:  (physics) an onium where the bound antiparticle-particle pair is a pion and an antipion.

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