Usually means: Ejecting electrons using light energy.
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We found 3 dictionaries that define the word photoionize:

General (3 matching dictionaries)
  1. photoionize: Merriam-Webster
  2. photoionize: Collins English Dictionary
  3. photoionize: Wiktionary

(Note: See photoionization as well.)

Definitions from Wiktionary (photoionize)

verb:  (physics) To cause, or to undergo photoionization

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