Might mean (unverified): Introduction of /j/ sound phonetically.
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We found 2 dictionaries that define the word iotation:

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  1. iotation: Wiktionary
  2. Iotation: Wikipedia, the Free Encyclopedia

Definitions from Wiktionary (iotation)

noun:  (linguistics) A specific occurrence of palatalization that occurred in the Proto-Slavic language, in which a consonant combined with the palatal approximant /j/ to form a palatalized consonant.
noun:  (linguistics) Any similar process occurring in a later Slavic language or elsewhere.

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