Usually means: Transfer between different semiconductor energy valleys.
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We found 3 dictionaries that define the word intervalley:

General (3 matching dictionaries)
  1. intervalley: Merriam-Webster
  2. intervalley: Collins English Dictionary
  3. intervalley: Wiktionary

Definitions from Wiktionary (intervalley)

adjective:  Between valleys.
noun:  A valley lying between other valleys, or between other entities.

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