Usually means: Atoms at each face's center.
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We found 6 dictionaries that define the word face-centered:

General (6 matching dictionaries)
  1. face-centered: Merriam-Webster
  2. face-centered: Oxford Learner's Dictionaries
  3. face-centered: Wiktionary
  4. face-centered: Infoplease Dictionary
  5. face-centered: Dictionary.com
  6. face-centered: TheFreeDictionary.com

Definitions from Wiktionary (face-centered)

adjective:  Having an atom at the centre of each face and one at each vertex (of a cubic crystal lattice)

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