Might mean (unverified): Attachment of cholesterol to molecules.
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We found one dictionary that defines the word cholesterylation:

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  1. cholesterylation: Wiktionary

Definitions from Wiktionary (cholesterylation)

noun:  (organic chemistry) Reaction with a cholesteryl group
noun:  (biochemistry) Specifically, the posttranslational reaction of cholesterol with a protein

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