Usually means: Spontaneous ion formation from molecules.
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We found 10 dictionaries that define the word autoionization:

General (8 matching dictionaries)
  1. autoionization: Merriam-Webster
  2. autoionization: Collins English Dictionary
  3. autoionization: Wiktionary
  4. autoionization: Dictionary.com
  5. Autoionization: Wikipedia, the Free Encyclopedia
  6. autoionization: Stammtisch Beau Fleuve Acronyms
  7. autoionization: TheFreeDictionary.com
  8. autoionization: Merriam-Webster

Computing (1 matching dictionary)
  1. autoionization: Encyclopedia

Science (1 matching dictionary)
  1. Chemistry Dictionary (No longer online)

Definitions from Wiktionary (autoionization)

noun:  A process by which atoms or molecules spontaneously transition from an electrically neutral state to a lower-energy ionized state

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