Might mean (unverified): Self-ionization of a compound occurs.
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We found 2 dictionaries that define the word autoionisation:

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  1. autoionisation: Collins English Dictionary
  2. autoionisation: Wiktionary

Definitions from Wiktionary (Autoionisation)

noun:  Alternative form of autoionization [A process by which atoms or molecules spontaneously transition from an electrically neutral state to a lower-energy ionized state]

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