Sorry, no online dictionaries contain the exact phrase opposite of mediate.
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Reverse dictionary results:
1. mediate! (there is no opposite of mediate
 2. as it means to intervene or bring about resolution between two parties.)
3. interpose
4. mediated
5. broker
6. intermediate
7. liaise
8. mediation
9. referee
10. evidence
 11. evidenced
12. intervention
13. remote
14. antithesis
15. bear
16. blow
17. come
18. conjugate
19. counter
20. counteract
 21. counterbalance
22. deny
23. dissuade
24. distal
25. egest
26. emit
27. eon
28. exhale
29. for
30. lace
 31. neutralize
32. neutralized
33. noon
34. nose
35. omit
36. ooze
37. play
38. polarize
39. quit
40. receive

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