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We found 3 dictionaries that define the word frontier orbital:

General (3 matching dictionaries)
  1. frontier orbital: Collins English Dictionary
  2. frontier orbital: Wiktionary
  3. frontier orbital: TheFreeDictionary.com

Definitions from Wiktionary (frontier orbital)

noun:  (chemistry) Either of a pair of orbitals, of two molecules or fragments, that overlap to form a bond; especially the HOMO and LUMO orbitals

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